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playbink "mw_end.bik" 1
The second argument indicates whether or not you want to be able to skip the movie. Since I presume you don't want the "full cinematic experience" here, leaving it just the way it is should be fine.
As far as I know, it'll search both the videos directory on the root of the CD drive you used to install the game, and the one within your data files folder. Any BINK format video will do, including an arbitrary-length stream of null charachters -- no need to inform the game of anything.